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Development of Novel Hydrogen-Bond Donor Catalysts - 9784431542308
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Item specifics
- Condition
- Book Title
- Development of Novel Hydrogen-Bond Donor Catalysts
- ISBN
- 9784431542308
- Publication Year
- 2013
- Type
- Textbook
- Format
- Hardcover
- Language
- English
- Publication Name
- Development of Novel Hydrogen-Bond Donor Catalysts
- Item Height
- 235mm
- Publisher
- Springer Verlag, Japan
- Item Width
- 155mm
- Subject
- Chemistry
- Item Weight
- 360g
- Number of Pages
- 107 Pages
About this product
Product Information
This work describes novel, effective hydrogen-bond (HB) donor catalysts based on a known bifunctional tertiary amine-thiourea, a privileged structure, which has been proven to be one of the most widely used organocatalysts. These HB donor catalysts derived from quinazoline and benzothiadiazine were initially synthesized as novel HB donors with their HB-donating abilities being measured by analytical methods. They were found to be effective for a variety of asymmetric transformations including Michael reactions of a, b-unsaturated imides and hydrazination reactions of 1,3-dicarbonyl compounds. Thiourea catalysts that have an additional functional group are also described. Specifically, thioureas that bear a hydroxyl group were synthesized and subsequently used as novel bifunctional organocatalysts for catalytic, asymmetric Petasis-type reactions involving organoboronic acids as nucleophiles. These addition reactions were difficult to achieve using existing organocatalysts. One of the developed catalytic methods can be applied to the synthesis of biologically interesting peptide-derived compounds possessing unnatural vinyl glycine moieties. These findings introduce new criteria required for the development of organocatalysts for asymmetric reactions, thus making a significant contribution to the field of organocatalysis.
Product Identifiers
Publisher
Springer Verlag, Japan
ISBN-13
9784431542308
eBay Product ID (ePID)
178250244
Product Key Features
Publication Name
Development of Novel Hydrogen-Bond Donor Catalysts
Format
Hardcover
Language
English
Subject
Chemistry
Publication Year
2013
Type
Textbook
Number of Pages
107 Pages
Dimensions
Item Height
235mm
Item Width
155mm
Item Weight
360g
Additional Product Features
Series Title
Springer Theses
Country/Region of Manufacture
Japan
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BOOKS ETC LIMITED
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