IllustratedYes
Table Of ContentPreface ix Solutions Summary 1 Problem 1 (1-iodopropane) 7 Problem 2 (2-butanone) 11 Problem 3 (2-hexanone) 15 Problem 4 (ethyl propionate) 19 Problem 5 (ethyl 3-ethoxypropionate) 23 Problem 6 (4-acetylbutyric acid) 28 Problem 7 (3-ethoxypropionyl chloride) 32 Problem 8 (ethyl 3-chloropropionate) 36 Problem 9 (isoamyl acetate) 40 Problem 10 (trans-4-hexen-3-one) 45 Problem 11 (trans-2-octen-4-one) 50 Problem 12 (3-nitrobenzaldehyde) 55 Problem 13 (3-iodotoluene) 61 Problem 14 (8-hydroxy-5-nitroquinoline) 64 Problem 15 (2-bromo-3-picoline) 69 Problem 16 (trans-anethole) 72 Problem 17 (cis-2-pentene) 75 Problem 18 (p-tolyl benzoate) 79 Problem 19 (phenyl p-toluate) 86 Problem 20 (4-biphenylyl acetate) 93 Problem 21 (4 ' -phenoxyacetophenone) 99 Problem 22 (4 ' -tert-butylacetophenone) 106 Problem 23 (2,2,4 ' -trimethylpropiophenone) 110 Problem 24 (trans-2-methyl-3-phenyl-2-propen-1-ol) 114 Problem 25 (methyl 4-ethoxybenzoate) 119 Problem 26 (methyl 3-(p-tolyl)propionate) 123 Problem 27 (4-(4 ' -methoxyphenyl)-2-butanone) 127 Problem 28 (ethyl 6-bromohexanoate) 132 Problem 29 (piperonal) 135 Problem 30 (cis-3-hexenyl benzoate) 139 Problem 31 (trans-2,cis-6-nonadienal) 146 Problem 32 (allyl glycidyl ether) 155 Problem 33 (3,4-epoxy-4-methyl-2-pentanone) 159 Problem 34 (dl-methionine) 162 Problem 35 (N-acetyl-l-leucine) 165 Problem 36 (isoamyl valerate) 170 Problem 37 ((E)-4-methyl-4 ' -nitrostilbene) 173 Problem 38 (2-tert-butyl-6-methylphenol) 181 Problem 39 (2-allyl-6-methylphenol) 186 Problem 40 (2-hydroxy-4-methoxybenzaldehyde) 194 Problem 41 (2 ' -hydroxy-5 ' -methylacetophenone) 198 Problem 42 (3 ' -fluoro-4 ' -methoxyacetophenone) 203 Problem 43 (trans-ferulic acid) 209 Problem 44 (sec-butyl 3-hydroxycinnamate) 215 Problem 45 (1-benzosuberone) 221 Problem 46 (dimethyl (3-bromopropyl)phosphonate) 228 Problem 47 (caffeine) 233 Problem 48 (benzyloxypropionitrile) 238 Problem 49 (cineole) 242 Problem 50 (thymoquinone) 246 Problem 51 (4-bromo-1-indanol) 251 Problem 52 (1-bromo-4-methylnaphthalene) 257 Problem 53 (carvacrol) 264 Problem 54 (acetoacetanilide) 272 Problem 55 (ethyl acetamidocyanoacetate) 277 Problem 56 (α-humulene) 283 Problem 57 (3,4-dihydro-2H-benzopyran-3-carboxylic acid) 289 Problem 58 (quinidine) 296 Problem 59 (salbutamol) 312 Problem 60 (2-hydroxy-1-naphthaldehyde) 322 Problem 61 (6-methyl-4-chromanone) 329 Problem 62 (citronellal) 336 Problem 63 ((+)-cis-2-oxabicyclo-[3.3.0]oct-6-en-3-one) 344 Problem 64 (melatonin) 349 Problem 65 (carvone) 362 Problem 66 (haloperidol) 370
Edition DescriptionStudent Manual
SynopsisThe derivation of structural information from spectroscopic data is now an integral part of organic chemistry courses at all Universities. Over recent years, a number of powerful two-dimensional NMR techniques ( e.g., The text Organic Structures from 2D NMR Spectra contains a graded set of structural problems employing 2D-NMR spectroscopy. The Instructors Guide and Solutions Manual to Organic Structures from 2D NMR Spectra is a set of step-by-step worked solutions to every problem in Organic Structures from 2D NMR Spectra. While it is absolutely clear that there are many ways to get to the correct solution of any of the problems, the instructors guide contains at least one complete pathway to every one of the questions. In addition, the instructors guide carefully rationalises every peak in every spectrum in relation to the correct structure. The Instructors Guide and Solutions Manual to Organic Structures from 2D NMR Spectra: Is a complete set of worked solutions to the problems contained in Organic Structures from 2D NMR Spectra. Provides a step-by-step description of the process to derive structures from spectra as well as annotated 2D spectra indicating the origin of every cross peak. Highlights common artefacts and re-enforces the important characteristics of the most common techniques 2D NMR techniques including COSY, NOESY, HMBC, TOCSY, CH-Correlation and multiplicity-edited C-H Correlation. This guide is an essential aid to those teachers, lecturers and instructors who use Organic Structures from 2D NMR as a text to teach students of Chemistry, Pharmacy, Biochemistry and those taking courses in Organic Chemistry., The derivation of structural information from spectroscopic data is now an integral part of organic chemistry courses at all Universities. Over recent years, a number of powerful two-dimensional NMR techniques ( e.g. HSQC, HMBC, TOCSY, COSY and NOESY) have been developed and these have vastly expanded the amount of structural information that can be obtained by NMR spectroscopy. Improvements in NMR instrumentation now mean that 2D NMR spectra are routinely (and sometimes automatically) acquired during the identification and characterisation of organic compounds. Organic Structures from 2D NMR Spectra is a carefully chosen set of more than 60 structural problems employing 2D-NMR spectroscopy. The problems are graded to develop and consolidate a student's understanding of 2D NMR spectroscopy. There are many easy problems at the beginning of the collection, to build confidence and demonstrate the basic principles from which structural information can be extracted using 2D NMR. The accompanying text is very descriptive and focussed on explaining the underlying theory at the most appropriate level to sufficiently tackle the problems. Organic Structures from 2D NMR Spectra Is a graded series of about 60 problems in 2D NMR spectroscopy that assumes a basic knowledge of organic chemistry and a basic knowledge of one-dimensional NMR spectroscopy Incorporates the basic theory behind 2D NMR and those common 2D NMR experiments that have proved most useful in solving structural problems in organic chemistry Focuses on the most common 2D NMR techniques - including COSY, NOESY, HMBC, TOCSY, CH-Correlation and multiplicity-edited C-H Correlation. Incorporates several examples containing the heteronuclei 31P, 15N and 19F Organic Structures from 2D NMR Spectra is a logical follow-on from the highly successful " Organic Structures from Spectra " which is now in its fifth edition. The book will be invaluable for students of Chemistry, Pharmacy, Biochemistry and those taking courses in Organic Chemistry. Also available: Instructors Guide and Solutions Manual to Organic Structures from 2D NMR Spectra