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The Chemistry of Rotational Isomers, Oki, Michinori 9783642510267 New<- - Picture 1 of 1

The Chemistry of Rotational Isomers by Michinori Oki (Paperback, 2012)

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Publisher: Springer ISBN 13: 9783642510267. Used-like N : The book pretty much look like a new book. There will be no stains or markings on the book, the cover is clean and crisp, the book will look unread, the only marks there may be are slight bumping marks to the edges of the book where it may have been on a shelf previously.

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Rotation about the Carbon-Carbon single bond is generally regarded to be unrestricted. About 50 years ago, rotational isomers were found to exhibit optical activity: substituted biphenyl derivatives. However, the author has investigated other classes of compounds that have stable rotational isomers at room temperature. These compounds can serve as models for studying very weak intermolecular interactions, that are difficult to observe. Even diastereotopic groups show different chemical reactivity. From the contents: The Free Rotation Concept - Rotamer Populations - Barriers to Rotation - Reactivity of Rotational Isomers.